Browsing by Author "Perera,K Sarath D"
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Item Insertion and deinsertion reactions(Institute of Chemistry Ceylon, 2020-09) Perera,K Sarath DIn an insertion reaction, Y gets transferred on to a ligand (AB). This can be considered as a migration reaction as shown belowItem Metal Hydrides(Institute of Chemistry Ceylon, 2021-04) Perera,K Sarath DWe know that main group hydrides such as LiAlH4 and NaBH4 are the common reducing agents used by organic chemists to reduce aldehydes, ketones and carboxylic acids. Transition metal hydrides act as good catalysts for hydrogenation, isomerization, hydroformylation and hydrocyanation of olefins. The coordination modes of the hydride ligand are as follows.